碳-氫鍵活化是一種將碳-氫鍵裂解并用碳-X鍵(其中X通常是碳、氧或氮)取代的反應(yīng)。該術(shù)語(yǔ)通常意味著過(guò)渡金屬參與C-H裂解過(guò)程。由該術(shù)語(yǔ)分類(lèi)的反應(yīng)通常涉及烴類(lèi)首先與金屬催化劑反應(yīng)以產(chǎn)生有機(jī)金屬配合物，其中烴類(lèi)與通過(guò)中間體“烷烴或芳烴絡(luò)合物”或作為過(guò)渡狀態(tài)而導(dǎo)致“M-C”中間體的金屬。第一步的中間體(稱(chēng)為C-H活化，有時(shí)與C-H官能化可互換使用)可隨后經(jīng)歷促進(jìn)反應(yīng)的反應(yīng)。
Dichloro(mesitylene)ruthenium(ii) dimer
1,3-Bis(diphenylphosphino)propane nickel(II)chloride
Bis(hexafluoroacetylacetonato)nickel(II)
Copper(I) tetra(acetonitrile) tetrafluoroborate
Tris(dibenzylideneacetone)dipalladium(0)
21H,23H-Porphine, 5,10,15,20-tetraphenyl-, iron complex
(Acetylacetonato)(1,5-cyclooctadiene)iridium(I)
Iridium(III) acetylacetonate
Iridium(III) chloride xhydrate
Iron(II) bromide
Iron(II) acetate
1,1'-Bis(di-tert-butylphosphino)ferrocene-palladium dichloride
Bis(1,5-cyclooctadiene)dimethoxydiiridium
Dichlorobis(tri-o-tolylphosphine)palladium(II)
[1,3-Bis(diphenylphosphino)propane]palladium(II) dichloride
Bis[cinnamyl palladium(II) chloride]
5,10,15,20-Tetraphenyl-21H,23H-porphine cobalt(II)
Tetrakis(acetonitrile)palladium(II) Ditriflate
[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)
Tetrakis[N-phthaloyl-(S)-tert-leucinato]dirhodium Bis(ethyl Acetate) Adduct
Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)] palladium(II)
Nickel(II) trifluoromethanesulfonate
Chloro(1,5-hexadiene)rhodium(I),dimer
Acetylacetonatobis(ethylene)rhodium(I)
Dichlorotricarbonyl ruthenium(II) dimer
Nickel(II) p-toluenesulfonate
