碳-氫鍵活化是一種將碳-氫鍵裂解并用碳-X鍵(其中X通常是碳、氧或氮)取代的反應(yīng)。該術(shù)語通常意味著過渡金屬參與C-H裂解過程。由該術(shù)語分類的反應(yīng)通常涉及烴類首先與金屬催化劑反應(yīng)以產(chǎn)生有機(jī)金屬配合物，其中烴類與通過中間體“烷烴或芳烴絡(luò)合物”或作為過渡狀態(tài)而導(dǎo)致“M-C”中間體的金屬。第一步的中間體(稱為C-H活化，有時與C-H官能化可互換使用)可隨后經(jīng)歷促進(jìn)反應(yīng)的反應(yīng)。
trans-Bis(dicyclohexylphenylphosphino)nickel(II) chloride
(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate
Tris(hexafluoroacetylacetonato)iron (III)
Rhodium,(2,5-norbornadiene)(2,4-pentanedionato)-
Tetrakis[N-phthaloyl-(R)-tert-leucinato]dirhodium Bis(ethyl Acetate) Adduct
Bicyclo[2.2.1]hepta-2,5-diene-rhodium(I) chloride dimer
Bromo[(2,6-pyridinediyl)bis(3-methyl-1-imidazolyl-2-ylidene)]nickel bromide
[1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene]triphenylphosphine nickel(II) dichloride
2,6-Bis(di-tert-butylphosphinoxy)phenylchlorohydroiridium(III)
Chlorobis(ethylene)iridium(I) dimer
Nickel(II) acetylacetonate xhydrate
Nickel(II) benzenesulfonate
Bis(trifluoro-2,4-pentanedionato)cobalt(II)
Silverhexafluoroantimonate
Hexakis(acetate)tripalladium(II)
[1,3-BIs(2,6-diisopropylphenyl)imidazol-2-ylidene](1,3-diphenyl-1,3-propanedionato)copper(i)
CHloro[(1,2,3,4,5,6-eta)-2,2'',4,4'',6,6''-hexamethyl[1,1':3',1''-terphenyl]-2'-thiolato-kappas][triisopropylphosphine-kappap]ruthenium(ii)
CHloro[(1,2,3,4,5,6-eta)-2,2'',4,4'',6,6''-hexamethyl[1,1':3',1''-terphenyl]-2'-thiolato-kappas][tris(4-fluorophenyl)phosphine-kappap]ruthenium(ii)
Bis(1,10-phenanthroline)palladium(II) Bis(hexafluorophosphate)
(p-Cymene)bis(mesitylcarboxylato)ruthenium(II)
[(2-Dimethylamino)propyldiphenylphosphine]palladium(II) Dichloride
[8-[Bis(1-methylethyl)phosphino-κP]-5-fluoro-2-(2-pyridinyl-κN)quinoline-κN]dichloroiron
