碳-氫鍵活化是一種將碳-氫鍵裂解并用碳-X鍵(其中X通常是碳、氧或氮)取代的反應(yīng)。該術(shù)語(yǔ)通常意味著過(guò)渡金屬參與C-H裂解過(guò)程。由該術(shù)語(yǔ)分類的反應(yīng)通常涉及烴類首先與金屬催化劑反應(yīng)以產(chǎn)生有機(jī)金屬配合物，其中烴類與通過(guò)中間體“烷烴或芳烴絡(luò)合物”或作為過(guò)渡狀態(tài)而導(dǎo)致“M-C”中間體的金屬。第一步的中間體(稱為C-H活化，有時(shí)與C-H官能化可互換使用)可隨后經(jīng)歷促進(jìn)反應(yīng)的反應(yīng)。
(Hexamethylbenzene)ruthenium(II) dichloride dimer
Tetrakis[n-tetrachlorophthaloyl-(s)-tert-leucinato]dirhodium bis(ethyl acetate) adduct
Tetrakis[N-phthaloyl-(S)-phenylalaninato]dirhodium ethyl acetate adduct
Allylpalladium(II) chloride
Ruthenium(III) chloride xhydrate
Palladium(II) 2,2,2-trifluoroacetate
Dichloro(benzene)ruthenium(II) dimer
[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)
[1,1'-Bis(diphenylphosphino)ferrocene]dichlorocobalt(II)
Bis[rhodium(α,α,α',α'-tetramethyl-1,3-benzenedipropionic acid)]
Chlorobis(cyclooctene)iridium(I)dimer
(R,R)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)
Cobalt(II) bis(acetylacetonate)
Rhodium(II) Octanoate Dimer
Dirhodium tetraacetate
[1,3-Bis(2,6-Diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(II) dichloride
[1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper chloride
Triruthenium dodecacarbonyl
Tris(2,4-pentanedionato)ruthenium(III)
N,N'-Ethylenebis(salicylideneiminato)cobalt(II)
1,4-Butylenebis(diphenylphosphine)palladium dichloride
Carbonylchloro bis(triphenylphosphine)iridium(I)
Carbonylhydridotris(triphenylphosphine)rhodium(I)
(5,10,15,20-Tetraphenylporphinato)manganese(III) chloride
Chloro(1,5-cyclooctadiene)iridium(I) dimer
